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The efficiency of separation of adducts of guanine by 1,2-bis(9-anthryl)ethylenediamine (BAde) and 2,7-bis(9-anthryl)-9,10-dihydro-9,10-dihydroxy-1,2,7,8-tetracarboxyfluorene (BAdtetra) was evaluated by using UV-vis spectroscopy and circular dichroism, and the mechanism of the separation was assessed. By isolating the adducts, we could show that intercalated trioxalatoguanine (3Guan/tG) was a major product and, as 3Guan/tG is not stable, the hypothesis of prior ring opening was confirmed. The rate of the opening of the adducts was measured by their ability to transfer to oxidized DNA. The reduction potential of the imidazo[4,5-f][1,10]phenanthroline (IP) ligand in BAdtetra was estimated to be 0.43 V vs Ag+/Ag, and this value was used to estimate the reduction potential of the guanine radical. Quantitative amounts of the two adducts separated by this method were used to measure the reduction potential of a single adduct and that of the complex adduct. Both adducts showed a semiquinone signal at -0.1 V vs Ag+/Ag. The reduction potential of the complex was the same as that of the adduct, indicating that little electron transfer occurred

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The present invention relates to a thermally-insulating layer applied to the surface of a glass substrate used in producing a semiconductor device.
2. Description of the Related Art
Semiconductor devices are subjected to processing such as the application of a thin film of a semiconductor, a conductor, an insulator or a semiconductor (or insulator).
Therefore, in order to achieve a semiconductor device having the desired characteristics, thin films of the above materials must be formed at desired locations in a semiconductor substrate. Here, the surface of a glass substrate on which a film or a thin film is to be formed in the semiconductor substrate must be covered with a surface protective film.
As for the above thin film process, a technology is known in which a surface protective film is applied to a glass substrate, and then the resultant structure is heated (hereinafter, referred to as “thermal annealing”) to provide a semiconductor device.
A known method of forming a surface protective film on a glass substrate will be described below.
A glass substrate is provided, for example, as an array substrate of a thin film transistor, that is, a semiconductor device, or the like. The glass substrate is subjected to a process including the steps of cleaning the glass substrate with deionized water (hereinafter, referred to as “dip in deionized water”), drying the cleaned glass substrate (a step S1), applying an alkali solution or a hydrogen peroxide solution onto the surface of the glass substrate (a step S2), and heating the applied alkali solution or hydrogen peroxide solution (hereinafter, referred to as “heat treatment”) (a step S3).
The glass substrate is heated to a temperature of, for example, from 200° C. to 700° C. in the heat treatment step S3. The heat treatment step is generally performed in a semiconductor device production line. After the above steps, the glass substrate is washed (Steps S4 and S5). The resultant surface of the glass substrate is protected from a mechanical damage.
In the above process, as for a surface protective film, a material that has excellent properties such as ad

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